Combining Organic and Non-Organic pigments to improve LightfastnessApproveRejectUn-ApproveSubscribeUn-Unsubscribe
Question asked 2020-11-26 08:16:25 ...
Most recent comment 2020-12-01 18:21:41
Pigments
Scientific Analysis
Technical Art History
Hi all,
From what I understand about pigments and from what I have read in articles from the paint coating industry, some non-Organic pigments have the ability to absorb rather than reflect UV light and without being so affected by the UV rays as most organic pigments can be.
I am thinking here of Iron Oxides, Nickel Antimony Titanium Yellow Rutile (PY53), and Chrome Antimony Titanate (PBr24) .
I believe from what I have read that the paint coating industry offer mixes of inorganic mineral pigments like this with much more chromatic organic pigments to improve lightfastness as well as opacity and reduce cost.
Am I correct in this assumption, and that if I mix say PY74 with PY53 (which is a weak tinter), or PR254 with PR101 I will improve lightfastness of the organic pigment on it's own at the expense of Chroma?
Thank you for your help,
Richard Phipps
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Moderator Answer
(george o'hanlon)
Combining organic and inorganic pigments in paint is a strategy recommended by coatings experts to offset the potential light-induced fading and weathering of organic pigments with inorganic pigments. Organic pigments offer higher color saturation while lowering cost of coatings. Inorganic pigments typically have better weatherability.
While this is a good strategy for commercial coatings, such as architectural coatings, implementing such a strategy in commercial artists’ paints is impractical.
Artists can create these types of mixtures, but it does require advanced knowledge of the compatibility of individual organic and inorganic pigments, many of which are presently not known, and must be tested.
Some organic pigments may have sufficient lightfastness, such as arylide yellow (PY74) and pyrrole red (PR254), on their own in fine art. The issue for architectural coatings is that coatings must also have very good weatherability, which pigments used in indoor applications do not require.
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Moderator Answer
(brian baade)
Just back from a vacation from the internet for the holiday
here in North America.
I believe that George is relaying that recent preliminary
test have shown that certain contemporary pigments perform differently when
mixed with different pigments (eg a certain color may have a particular lightfastness
rating when mixed with one color, and another when mixed with a different
color). This is all very preliminary and may not turn out to be a big deal. Far
more testing is needed to assess this phenomenon.
As to the central point of your question, it is very
unlikely that adding a stable inorganic pigment to a less than stable organic
pigment would drastically protect the fugitive component. It is true that some
pigments do absorb UV, zinc white is one, which is why it was/is a major
component in some sunscreens. This does not mean that the benefit would render
the mixture lightfast, only an improvement. The organic colorant would still receive the
energy from the light. As a corollary, it was very common practice in the 17th
century to mix yellow lake pigments with azurite or even lapis ultramarine to create
rich greens. The yellows eventually faded leaving blue leaves and foliage. Even
as late as Edward Hopper we see green made from stable blues and fugitive
modern organic yellows that have faded resulting in blue trees. Cost and
opacity are probably far bigger factors for industry. Most, but not all, of the
brilliant organic pigments today are very transparent (Pyrrole
Red is one of the exceptions, and it is very robust). The super-saturated
organic colors are also often far more expensive than their inorganic
counterparts (like everything there are exceptions to this, and the intensity of
many organic pigments means that far less needs to be added to a mixture to create
a brilliant effect).
UV absorbers and scavengers added to varnish would likely
offer much more protection. They would never
be added to oil paint where they would inhibit proper oxidation.
Others will probably add other caveats to these pronouncements and some may even contradict a point or two,
but that is why this is a forum and not a sacred text 😉
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Moderator Answer
(brian baade)
It could not hurt :)
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