Artist's rectified turpentine caused white "rings" on my oil paintingApproveRejectUn-ApproveSubscribeUn-Unsubscribe
Question asked 2021-10-22 01:07:38 ...
Most recent comment 2021-12-11 05:33:29
Oil Paint
Solvents and Thinners
Hi MITRA, 20211022_005347.jpg
I began a large oil on linen several years ago, and picked it back up again when I received grant funds to complete the project.
In a case of "what's done is done", since I'd had good luck in the past with cleaning spots/stains off of an in-progress painting with artist's recified turpentine then cleaning off any potential residue with OMS, that was the approach I took earlier this week on one area of this painting. As soon as the solvents dried, I saw a faint white residue that was comprised of many whitish "rings." I had used a freshly-laundered rag that had previously been used for oil painting, so I came back in with another treatment of OMS and a new clean rag, thinking that perhaps a thin veneer of oil that made it through the laundering process had been deposited by the rag. It got a little better (and when the surface was wet with OMS it looked fine), but once the OMS dried, the rings were still there. It kind of looks like a patterned version of sinking in. I wondered if something migrated up, or if I disturbed the binder too much, etc when I cleaned the surface with the turps?
I use a high-quality paint with a walnut oil binder, so there shouldn't be any impurities in the paint itself. I also follow the fat-over-lean rules, and never adulterate my paint more than 20%. I had started this work with a solvent-based alkyd oil medium, then switched to the walnut alkyd oil medium, though the affected area is comprised of just a couple of layers with the original medium. I do plan to overpaint, though I had been planning to just add highlights and shadows to this region rather than overpaint the entire area -- though if that's what I need to now do, I will. I'm also wondering if varnishing later will take care of it?
I've attached a photograph for your reference. It looks like the whitish shapes settled into texture made by the hand-applied acrylic dispersion primer "gesso", because the paint layers themselves are fairly smooth and applied mechanically thin. (Incidentally, this surface texture is only visible by zooming in on the photo -- it isn't apparent to the naked eye or touch -- and it seems like if the turps bit into the paint layer enough to create the texture, that it would either have revealed the underpainting or the white primer.)
This particular painting is part of a larger project for which I have a deadline. It is a very large canvas, so for both monetary and time reasons, starting over isn't an option. I definitely hope that you won't think it is necessary.
Thanks in advance for your help and advice. I do hope you'll have good news for me and that this won't cause any adhesion problems down the road. Fingers crossed that it is easily remedied.
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Moderator Answer
(brian baade)
The photos do not really show enough to really give me sense
of what is being deposited and causing a ring. Obviously, the solvents
dissolved something, and it accumulated at the edge of the drying zone to
create a bit of a ring. This is not really that obvious in your images, but we
take you at your word.
Here is my general criteria when dealing with surface issues
before eventual varnishing: In general, and this is, of course an over
simplification, if you are going to apply a significant varnish, meaning that
it will substantially change the surface gloss, the final appearance will be
very similar, but slightly less glossy, than the appearance of the same surface
when flooded with odorless mineral spirits. Please do no sue me it you notice
small differences but whetting up with a very low polarity solvent is one of
the ways in which we as painting conservators ascertain how our painting
conservation treatment will eventually look before we apply the final varnish.
EditDelete
Moderator Answer
(brian baade)
As an aside, there are many possible materials in even “quality”
paints that could be picked up and be mobile to create possible rings.
Stabilizers and waxes could certainly be dissolved and then migrate to tide
line air interfaces. Unbound fatty acids could do so as well. Organic materials
are unruly beasts 😉
EditDelete
Moderator Answer
(brian baade)
This does not sound like a major issue to me. Likely, you
will be fine. Yes, the issue with sanding is more about making possibly toxic
particles airborne. This can be dealt with by carefully wet sanding using a
small amount of mineral spirits or even water if the painting can take that.
The other possible problem with sanding is that if done carelessly or too rigorously,
one could inadvertently remove too much surface and create a damaged texture or
a too smooth spot. Sanding is even more problematic with glazed and indirectly
painted imagery, but that is probably obvious to all.
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